Peak Oil Introduction: An Historical and Scientific Perspective

There are those who still think that they are holding the pass against a revolution that may be coming up the road. But they are gazing in the wrong direction. The revolution is behind them. It went by in the Night of Depression singing songs to freedom. Garet Garret

The great French chemist Marcellin Berthelot particularly scorned the hypothesis of a biological origin for petroleum. Berthelot first carried out experiments involving, among others, a series of what are now referred to as Kolbe reactions and demonstrated the generation of petroleum by dissolving steel in strong acid. He produced the suite of n-alkanes and made it plain that such were generated in total absence of any "biological" molecule or process. Berthelot's investigations were later extended and refined by other scientists, including Biasson and Sokolov, all of whom observed similar phenomena and likewise concluded that petroleum was unconnected to biological matter.

During the last quarter of the nineteenth century, the great Russian chemist Dmitri Mendeleev also examined and rejected Lomonosov's hypothesis of a biological origin for petroleum. In contrast to Berthelot who had made no suggestion as to where or how petroleum might have come, Mendeleev stated clearly that petroleum is a primordial material which has erupted from great depth. With extraordinary perception, Mendeleev hypothesized the existence of geological structures which he called "deep faults," and correctly identified such as the locus of weakness in the crust of the Earth via which petroleum would travel from the depths. After he made that hypothesis, Mendeleev was abusively criticized by the geologists of his time, for the notion of deep faults was then unknown. Today, of course, an understanding of plate tectonics would be unimaginable without recognition of deep faults.

3. The enunciation and development of modern petroleum science.

The impetus for development of modern petroleum science came shortly after the end of World War II, and was impelled by recognition by the government of the (then) U.S.S.R. of the crucial necessity of petroleum in modern warfare. In 1947, the U.S.S.R. had (as its petroleum "experts" then estimated) very limited petroleum reserves, of which the largest were the oil fields in the region of the Abseron peninsula, near the Caspian city Baku in the present country of Azerbaijan. At that time, the oil fields near Baku were considered to be "depleting" and "nearing exhaustion." During World War II, the Soviets had occupied the two northern provinces of Iran; in 1946, the British government had forced them out. By 1947, the Soviets realized that the American, British, and French were not going to allow them to operate in the middle east, nor in the petroleum producing areas of Africa, nor Indonesia, nor Burma, nor Malaysia, nor anywhere in the far east, nor in Latin America. The government of the Soviet Union recognized then that new petroleum reserves would have to be discovered and developed within the U.S.S.R.

The government of the Soviet Union initiated a "Manhattan Project" type program, which was given the highest priority to study every aspect of petroleum, to determine its origins and how petroleum reserves are generated, and to ascertain what might be the most effective strategies for petroleum exploration. At that time, Russia benefited from the excellent educational system which had been introduced after the 1917 revolution. The Russian petroleum community had then almost two generations of highly educated, scientifically competent men and women, ready to take up the problem of petroleum origins. Modern Russian petroleum science followed within five years.

In 1951, the modern Russian-Ukrainian theory of deep, abiotic petroleum origins was first enunciated by Nikolai A. Kudryavtsev at the All-Union petroleum geology congress. Kudryavtsev analyzed the hypothesis of a biological origin of petroleum, and pointed out the failures of the claims then commonly put forth to support that hypothesis. Kudryavtsev was soon joined by numerous other Russian and Ukrainian geologists, among the first of whom were P. N. Kropotkin, K. A. Shakhvarstova, G. N. Dolenko, V. F. Linetskii, V. B. Porfir'yev, and K. A. Anikiev.

During the first decade of its existence, the modern theory of petroleum origins was the subject of great contention and controversy. Between the years 1951 and 1965, with the leadership of Kudryavtsev and Porfir'yev, increasing numbers of geologists published articles demonstrating the failures and inconsistencies inherent in the old "biogenic origin" hypothesis. With the passing of the first decade of the modern theory, the failure of the previous, eighteenth century hypothesis of an origin of petroleum from biological detritus in the near-surface sediments had been thoroughly demonstrated, the hypothesis of Lomonosov discredited, and the modern theory firmly established.

An important point to be recognized is that the modern Russian-Ukrainian theory of abiotic petroleum origins was, initially, a geologists' theory. Kudryavtsev, Kropotkin, Dolenko, Porfir'yev and the developers of the modern theory of petroleum were all geologists. Their arguments were necessarily those of geologists, developed from many observations, and much data, organized into a pattern, and argued by persuasion.

By contrast, the practice of mainstream, predictive modern science, particularly physics and chemistry, involves a minimum of observation or data, and applies only a minimum of physical law, inevitably expressed with formal mathematics, and argues by compulsion. Such predictive proof of the geologists assertions for the modern Russian-Ukrainian theory of deep, abiotic petroleum origins had to wait almost a half century, for such required the development not only of modern quantum statistical mechanics but also that of the techniques of many-body theory and the application of statistical geometry to the analysis of dense fluids, designated scaled particle theory.

3. The organization of these papers.

The papers collected on the following public-access pages of this web site [ http://www.gasresources.net ] are organized into several categories and sub-categories: The principle categories are the Scientific Publications; the Economic Publications; and the Political and Sociological Essays. The organization of the following papers does not follow the historical development of the modern Russian-Ukrainian theory of deep, abiotic petroleum origins but instead orders them according to the different aspects of modern petroleum science. A number of these papers were delivered at the International Conference on the Production of Petroleum from the Crystalline Basement, held in Kazan, Russia, June 2001, in celebration of the half-century commemoration of the enunciation of that theory by Nikolai Kudryavtsev.

3.1. The scientific and technical papers.

The Scientific Publications are further divided into two sets of articles dealing, first, with the rigorous scientific foundations upon which rests the modern Russian-Ukrainian theory of deep, abiotic petroleum origins, and, second, with applications of modern petroleum science to petroleum exploration and production.

In the first subsection are several published articles concerned directly with the statistical thermodynamics of the evolution of the hydrocarbon molecules and the origins of petroleum. The first paper in this section reviews the constraints of irreversibility upon the evolution of the hydrogen-carbon [H-C] system as determined by the second law of thermodynamics. In this article, the formalism of modern thermodynamics is applied freely, and the prohibition of spontaneous genesis of hydrocarbons heavier than methane in the regimes of temperature and pressure of the near-surface crust of the Earth is easily noted. A following paper reviews, and refutes, the claims for "evidence"[sic] for a biological origin of petroleum (commonly asserted in typical British and American textbooks on petroleum geology), - e.g., the "biomarkers," the observation of optical activity, the slight differences in the abundances of linear molecules with odd (or even) numbers of carbon atoms, the presence of porphyrins, etc. The claims for each (as evidence of a biotic connection for petroleum) are refuted, with unchallenged evidence published in first-rank scientific journals often as long as thirty or forty years ago. The continued, egregious claims of such as "evidence" of a biological origin of petroleum are acknowledged to be fraudulent. A recent paper describes very recent analysis of the thermodynamic stability of the hydrogen-carbon system in circumstances most favorable to the evolution of hydrocarbons, and shows that the hydrocarbons which comprise natural petroleum cannot evolve spontaneously at pressures less than approximately 30 kbar, which pressures correspond to the depths of the mantle of the Earth. In the second instance, this paper describes experimental demonstration of the foregoing theoretical predictions, whereby laboratory-pure solid marble (CaCO₃), iron oxide (FeO), wet with triple-distilled water, are subjected to pressures up to 50 kbar and temperatures to 2000 C. With no contribution of either hydrocarbons or biological detritus, the CaCO₃-FeO-H₂O system spontaneously generates, at the high pressures predicted theoretically, the suite of hydrocarbons characteristic of natural petroleum.

3.2 The economic publications.

The second main group of papers deals with the important issues connected with the economic consequences of modern Russian petroleum science. In these papers are reviewed both some of the pseudo-economic fables (e.g., "the human race is going to run out of natural petroleum") which have been traditionally connected with the error that petroleum is some sort of "fossil fuel," for reason (supposedly) of having evolved from biological detritus, - albeit in violation of the laws of chemical thermodynamics.

Considerations about Recent Predictions of Impending Shortages of
Petroleum Evaluated from the Perspective of Modern Petroleum Science, J. F. Kenney, (1996), Energy World, 240, 16-18.

The Exploration and Development of the Twelve Major and one Giant Oil and Gas Fields on the Northern Flank of the Dnieper-Donets Basin, V. A. Krayushkin, T. I. Tchebanenko, V. P. Klochko, Ye. S. Dvoryanin, J. F. Kenney, (2001), Energia, 22/3, 44-47.

The Global Energy Market in the Long Term: The Continuing Dominance of Affordable Non-Renewable Resources. P. Odell, lecture before the Swedish Academy of Sciences, (March 16, 2000)
.
Closed Coffin: Ending the Debate on "The End of Cheap Oil." M. C. Lynch, lecture before the International Energy Agency, Paris, 2001.

Farce this Time: Renewed Pessimism About Oil Supply. M. C. Lynch, Geopolitics of Energy, December 1998-January 1999.

The New Pessimism about Petroleum Resources: Debunking the 'Hubbert Model' (and Hubbert modelers). M. C. Lynch, Minerals and Energy, July 2004 (to be published.)

3.3 The political and sociological essays.

The third main group of papers deals with diverse sociological and political aspects which have involved the modern Russian-Ukrainian theory of deep, abiotic petroleum origins, and which have too often obstructed persons, and governments, in the U.S.A. from learning it. In this section, are examples of some of the published efforts to misrepresent modern Russian petroleum science.